Admin center - exported list of users fields vs user account fields



In the expported user list I can see feilds such as Division, Department, Cost center. I do not have access to these feilds when a user account is edited or created. except Department, which is not linked to the field in the user list. In the user account there are Title, Company, Job category a,d 2 feilds for phone, that don't show on the user list. I would like to be able to better categorize the users based on their department and teams, and be able to have the information both in the user account and on the user list we can export. I can I acheive that?